The Hardness of Aluminum Oxide Surface in Anodized Coloring Under Low Voltage

Authors

  • Haris Puspito Buwono Politeknik Negeri Malang
  • Syamsul Hadi
  • Mochamad Muzaki
  • Subagiyo Subagiyo
  • Lisa Agustriyana
  • Samsul Hadi
  • Nurchajat Nurchajat

DOI:

https://doi.org/10.31963/intek.v6i2.1522

Keywords:

anodized coloring, hardness, sulfuric acid, ink printer, hardness difference

Abstract

Coloring of aluminum oxide on the Aluminum type AA1100, which is the typical type for household appliances and purposes, through anodizing coloring process by the blue color of commercial printer ink had been successfully performed. The blue color was well adhered and was not easy to be removed by physical treatment such as wiping. The anodize coloring process includes chemical cleaning of aluminum surface, the formation of pores in the sulfuric acid solution at a specific current and a specified duration of time, coloring and closing the pores via sealing. It also shows the anodizing process increases aluminum oxide surface hardness increased by applying higher current density, and longer duration time of the process. The aluminum oxide hardness was in harmony to the duration of time processing, and current density; however, not in line to a concentration of the solution. The maximum hardness of the aluminum oxide layer obtained is 50 kg/mm2. The relation of current density and voltage, the effect of current density and sulfuric acid concentration toward aluminum oxide hardness were analyzed. Moreover, the difference of aluminum oxide hardness of the front side and backside to cathode also discussed.

References

D. A. L. Nicklen and D. R. Gabe, “No Title,†vol. 7, pp. 353–359, 1978.

D. Veys-Renaux, N. Chahboun, and E. Rocca, “Anodizing of multiphase aluminum alloys in sulfuric acid: in-situ electrochemical behavior and oxide properties,†Electrochim. Acta, vol. 211, pp. 1056–1065, 2016.

S. Theohari and C. Kontogeorgou, “Effect of temperature on the anodizing process of aluminum alloy AA 5052,†Appl. Surf. Sci., vol. 284, pp. 611–618, 2013.

H. Masuda, H. Yamada, M. Satoh, H. Asoh, M. Nakao, and T. Tamamura, “Highly ordered nanochannel-array architecture in anodic alumina,†Appl. Phys. Lett., vol. 71, no. 19, pp. 2770–2772, 1997.

O. Jessensky, “Self-Organized Formation of Hexagonal Pore Structures in Anodic Alumina,†J. Electrochem. Soc., vol. 145, no. 11, p. 3735, 1998.

C. K. Chung, M. W. Liao, H. C. Chang, and C. T. Lee, “Effects of temperature and voltage mode on nanoporous anodic aluminum oxide films by one-step anodization,†Thin Solid Films, vol. 520, no. 5, pp. 1554–1558, 2011.

G. D. Sulka, S. Stroobants, V. V. Moshchalkov, G. Borghs, and J.-P. Celis, “Effect of Tensile Stress on Growth of Self-Organized Nanostructures on Anodized Aluminum,†J. Electrochem. Soc., vol. 151, no. 5, p. B260, 2004.

H. Masuda, K. Yasui, Y. Sakamoto, M. Nakao, T. Tamamura, and K. Nishio, “Ideally ordered anodic porous alumina mask prepared by imprinting of vacuum-evaporated Al on Si,†Japanese J. Appl. Physics, Part 2 Lett., vol. 40, no. 11 B, pp. 1267–1269, 2001.

T. Kikuchi, T. Yamamoto, S. Natsui, and R. O. Suzuki, “Fabrication of anodic porous alumina by squaric acid anodizing,†Electrochim. Acta, vol. 123, pp. 14–22, 2014.

J. M. Vico, F. Jansen, K. Maex, G. Groeseneken, and P. M. Vereecken, “Formation of porous alumina patterns on silicon,†ECS Trans., vol. 3, no. 21, pp. 85–93, 2007.

L. E. Fratila-Apachitei et al., “A transmission electron microscopy study of hard anodic oxide layers on AlSi(Cu) alloys,†Electrochim. Acta, vol. 49, no. 19, pp. 3169–3177, 2004.

W. Lee, R. Ji, U. Gösele, and K. Nielsch, “Fast fabrication of long-range ordered porous alumina membranes by hard anodization,†Nat. Mater., vol. 5, no. 9, pp. 741–747, 2006.

I. S. Molchan, T. V. Molchan, N. V. Gaponenko, P. Skeldon, and G. E. Thompson, “Impurity-driven defect generation in porous anodic alumina,†Electrochem. commun., vol. 12, no. 5, pp. 693–696, 2010.

D. Losic, “Preparation of porous anodic alumina with periodically perforated pores,†Langmuir, vol. 25, no. 10, pp. 5426–5431, 2009.

W. J. Stȩpniowski and Z. Bojar, “Synthesis of anodic aluminum oxide (AAO) at relatively high temperatures. Study of the influence of anodization conditions on the alumina structural features,†Surf. Coatings Technol., vol. 206, no. 2–3, pp. 265–272, 2011.

G. D. Sulka, Highly Ordered Anodic Porous Alumina Formation by Self-Organized Anodizing. 2008.

G. D. Sulka and K. G. Parkoła, “Temperature influence on well-ordered nanopore structures grown by anodization of aluminum in sulphuric acid,†vol. 52, pp. 1880–1888, 2007.

I. C. Chung, C. K. Chung, and Y. K. Su, “Surface & Coatings Technology Effect of current density and concentration on microstructure and corrosion behavior of 6061 Al alloy in sulfuric acid,†vol. 313, pp. 299–306, 2017.

Published

2019-11-12