AKTIVASI ADSORBEN DARI RUMPUT LAUT SARGASSUM sp MENGGUNAKAN ASAM KLORIDA
Abstrak
One of those pollutants which contaminate the water is heavy metal. Some of the metal ion is a pretty dangerous waterpolluters are Cd, Pb, Zn, Hg, Cu and Fe. Various attempts have been made to address the problem of the pollution ofheavy metals, among others by making use of seaweed as adsorbent. This research aims to improve the capacity of theseaweed sargassum sp to absorb metal ion with chemical activation. Research includes several stages, namelypreparation of adsorbents, preparation of heavy metal waste, adsorbents activation with the hydrochloric acidconcentrations varied 0.1; 0.2; 0.3; and 0.4 N, optimization of time contact between adsorbent and waste varied 15, 30,45, 60, and 75 minutes, and the optimization of the adsorbent's weight varied 0.1; 0.5; 1; 1.5; and 1.85 g. This researchis done in batches by measuring the concentration of heavy metals before and after the adsorption of so knownquantities of heavy metals that can be diadsorpsi by the adsorbent by using atomic absorption spectrophotometer (AAS).Adsorption capacity of adsorbent improvement after activated will also be known by the way comparing with adsorbentwhich has not been activated. Adsorption capacity of sargassum sp the activated or not activated is not much different inabsorbing Pb ion. Optimum contact time is obtained at the time of 45 minutes with optimum weight 0.5 grams ofsargassum sp with Pb absorbed 99.74%.Referensi
Aryanti, L, 2011. Pemanfaatan Rumput Laut Sargassum Sp. Sebagai Adsorben Limbah Cair Industri Rumah Tangga
Perikanan.Skripsi. Instititut Pertanian Bogor.
Baral, S. S., Das, N., Chaudhury, G. R., and Das, S. N., 2009, “A preliminary study on the adsorptive removal of Cr(VI)
using seaweed, Hydrilla verticillata“, J. Hazardous Materials: 358-369.
Gufta FK. 1998. Utilization of bagasse fly ash generated in the sugar industry for removal and recovery of phenol and p-
Nitrophenol from wastewater. J Chem Technol Biotechnol 70: 180-186.
Mahbub, A.M., 2012. Studi Ekstraksi Alginat Dari Biomassa Rumput Laut Coklat (Sargassum Crassifolium) Sebagai
Adsorben Dalam Biosorpsi Ion Logam Cadmium (II), Depok: Program Studi Kimia Universitas Indonesia.
Raize O, Argaman Y, Yannai S. 2004. Mechanisms of biosorption of different heavy metals by brown marine
macroalgae. J. Biotechnology and Bioengineering 87(4): 451-458.
Rubin E, Rodriguez P, Herrero R, Cremade J, Barbara I, Manuel. 2005. Removal of methylene blue from aqueous
solutions using biosorbent Sargassum muticum : Aninvasive macroalga in Europe. J. Chemical Technology and
Biotechnology: 1-16.
Seki H, Akira S. 1998. Biosorption of heavy metal ions to brown algae, Macrocystis pyrifera, Kjellmamiella crassiforia,
and Undaria pinnatifida. J. Colloid and Interface Science 206 : 297-301.
Suzuki, Y., Kametani, T., Maruyama, T., 2005, Removal of heavy metals from aqueous solution by nonliving Ulva
seaweed as biosorbent, Water Research: 1803-1808.