PEMANFAATAN BATUBARA KUALITAS RENDAH SEBAGAI BAHAN KOKAS MELIBATKAN PROSES DESULFURISASI, DEMINERALISASI DAN KARBONISASI

Swastanti Brotowati, Pirman Pirman

Abstract


Coal from Mallawa village, Bone-Pangkep Regency of South Sulawesi included in young coal rank, with content of :
2.64% moisture, 46.16% of volatile matter, 15.26% ash, 35.96% fixed carbon, 1.73% sulfur and heat value of 5190
kcal / kgram this coal includes subbituminous coal category. This coal will be upgrade to be bituminous rank coal
through desulfurization and demineralization process and continued with carbonization process. The desulfurization
process using 20% HCl solution aims to reduce sulfur content, demineralization process using 20% NaOH solution to
decrease the ash content and carbonization process aims to reduce the content of volatile matter and to increase fixed
carbon content . Coal of subbituminus from Mallawa can be processed into coal bituminous, with desulfurization
process can reduce sulfur content from 1.73% to 0.365%, while in demineralization process can decrease ash content
from 15.26% to 9.98% and carbonization process at 500 oC with time for 240 minutes can be reduce of volatile matter
46.16% to 13.08%, while water content decreased from 2.64% to 1.16%, carbon content increase from 35.96%, to
85.67%, and the heat value increased from 5190 kcal / kgram become 7931,69 kkal / kgram. Coal with the content as
above can be categorized coal type bituminus or coking coal can be utilized as raw material of cokes.
Keyword : desulfurization ,demineralization, carbonization , coking coal

Full Text:

PDF

References


Adiarso, dkk. 2010, Teknologi Pemanfaatan Batubara Peluang dan Tantangan. Balai Besar Teknologi Energi

BPPT PUSPIPTEK,Tangerang

ASTM D 5142-02, 2010, Standards Test Methods for Proximate Analysis of The Analysis Sample of Coal and Coke

by Instrumental Procedures.

Budiraharjo, I.,2011: Industri batubara Indonesia. Terjemah bebas artikel berjudul “Indonesia sekitan jijou†oleh

Masafumi Uehara, JCOAL Journal Vol 18, Januari 2011. (JCOAL Resources Development Division)

Borthakur,S.danMukherjee,P.C.2001.Chemical Demineralization/Desulphurization of Sulphur Coal Using Sodium

Htdroxide and acid Solutions. May. Elsevier Science Ltd.

Erlina Yustanti, 2012., Pencampuran Batubara Cooking dengan Batubara Lignite Hasil Karbonisasi Sebagai Bahan

Pembuatan Kokas. Jurnal Teknologi Pengelolaan Limbah Radioakti) ISSN :1410-9565, Volume 15

Erwin J., dkk.2015.,Pengaruh suhu dan waktu karbonisasi terhadap nilai kalor dan karakteristik pada pembuatan

bioarang berbahan baku pelepah aren ,jurnal : Teknik Kimia USU, Vol. 4, No. 2.

Esthi K.,dkk.2017, Produksi Karbon Aktif dari Batubara Bituminus dengan Aktivasi Tunggal H3PO4, Kombinasi

H3PO4-NH4HCO3, dan Termal, Jurnal Reaktor, Vol. 17 No. 2, Juni, Hal. 74-80

Hartanto, Singgih dan Ratnawati, Pembuatan Karbon aktif dari Tempurung Kelapa Sawit dengan Metode Aktivasi

Kimia, Jurnal Sains Materi Indonesia, ISSN : 1411-1098, Vol. 12, No. 1, 2010.

Khairil & Irwansyah,2010, Kaji Eksperimental Teknologi Pembuatan Kokas dari Batubara sebagai Sumber Panas

dan Karbon pada Tanur Tinggi (Blast Furnace). Universitas Syiah Kuala, Aceh

Kirk, R.E.and Othmer, D.F.,1980, Encyclopedia of Chemical Technology, Interscience Inc. New

York.

Suganal, Kokas dari Batubara Non Coking Indonesia ,Prosiding Seminar Nasional XVIâ€Kimia dalam Industri dan

Lingkungan, Jaringan Kerjasama Kimia Indonesia, Yogyakarta, Desember 2007.


Refbacks

  • There are currently no refbacks.