PENENTUAN KONSENTRASI BIOSOLAR BERDASARKAN KARBON-14 DENGAN METODE LIQUID SCINTILLATION COUNTING (LSC)

Rahmawati Rahmawati, Alfian Noor, Maming Maming, Muhammad Zakir

Abstract


Biosolar is one of bio-fuels derived from biomass, especially from plants (vegetable material). Biosolar is sold
on the market consisting of a mixture of a number of products produced by the blending process of biodiesel with diesel
based on certain concentrations. Biodiesel is chemically formed by the process of transesterification and esterification
triglycerides are converted into methyl esters with the help of H2SO4 and NaOH as a catalyst. The determination of
biosolar concentrations was based on the radiocarbon method on the specific sample activity measurements obtained
from the Hidex 300 SL Liquid Scintilation Counting (LSC). The result showed that the total carbon of the sample
solution was 6.0113 g / 8 mL while the specific activity value was 5.0700 DPM / gC so that the biosolar concentration
can be determined by measuring the standard and specific activity through linear regression equation of 8.83%. Thus the
method of measuring the carbon-14 activity can be used to verify the biosolar concentrations produced by pertamina.


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References


Anggraini, Ananta Andy. 2002. Biodiesel dari Minyak Jelantah. KOMPAS. Diakses pada 15 Januari 2015.

Azmi, Riza dan Hidayat Amir. 2014. Ketahanan Energi: Konsep, Kebijakan dan Tantangan

Bagi Indonesia, Jakarta.

Balai Besar Laboratorium Kesehatan, 2014, Instruksi Kerja Metode Pemeriksaan C-Organik, Instalasi Kimia Kesehatan

Dan Toksikologi, Makassar.

Canducci, C., Bartolomei, P., Magnani, G., Rizzo, A., 2013, Upgrade Of The CO2 Direct Absorption Method For Low

Level 14C Liquid Scintillation Counting, Radiocarbon, 55 (2-3): 260-267.

Dijs, I.J, Vander Windt, E., Kaihola, L., vander Borg, K., 2006. Quantitative Determination By 14C Analysis Of The

Biological Component In Fuels. Radiocarbon, 48 (3):315–323.

Elistina, 2007, Akurasi Penentuan Kadar Tritium (3H) dalam Urin Menggunakan Indikator Quenching (Pemadam)

tSIE, Prosiding Pertemuan dan Presentasi Ilmiah Fungsional Pengembangan Teknologi Nuklir 1, Pusat Teknologi

Keselamatan dan Metrologi Radiasi, Badan Tenaga Atom Nasional, Jakarta.

Georgogianni, K. G., Kontiminas, M. G., Tegou, E., Avlonitis, D., dan Gergis, V., 2007. Biodiesel Production: Reaction

And Process Parameters Of Alkali-Catalyzed Transesterification Of Waste Frying Oils, Energy & Fuels, 21: 3023-

Kementerian Perindustrian Republik Indonesia, 2014, Pertamina Realisasikan Biofuel 10 Persen Esters, Berita Industri,

Jakarta.

Kristof, R., Hirsch, M., and Logard, J.K., 2014, Implementation of Direct LSC Method for Diesel Samples on The Fuel

Market, Applied Radiation and Isotopes, 1-5.

Kristof, R., and Logar, J.K., 2013, Direct LSC Method for Measurements of Biofuels in Fuel, Talanta, 1-6.

Libby, W.F., 1960, Radiocarbon Dating, Nobel Lecture, Elsevier Publishing Company, Amsterdam.

Maming, Noor, A., Zakir, M., Raya, I., Jauhari, Kartika, S.A., 2014, Aplication in Liquid Scintillation Method on

Carbon Dating in Determination of Coral Ages from Spermonde Archipelagos, Mar. Chim. Acta, 15(1): 31-35.

Noakes, J., Norton, G., Culp,R., Nigam,M., Dvoracek,D., 2006. A Comparison Of Analytica Lmethods For The

Certification Of Biobased Products. In: Chalupnik, S., Schonhofer,F., Noakes, J. (Eds.), LSC 2005, Advances in

Liquid Scintillation Spectrometry. Radiocarbon, Tuscon, pp. 259–271.

Satrio dan Abidin, Z., 2007, Perbandingan Metode Sintesis Benzena Dan Absorpsi CO2 Untuk Penanggalan Radioisotop

C, Jurnal Ilmiah Aplikasi Isotop Dan Radiasi, 3(1): 1-34.

Sholikhah, M.D., 2010, Pengembangan Metoda Kontrol Kualitas untuk Uji Mutu Biodiesel yang Dapat Diterapkan

Oleh Industri Kecil-Menengah, Laporan Akhir, Balai Rekayasa Desain dan Sistem Teknologi BPPT.

Susilo, B., 2006. Biodiesel Sumber Energi Alternatif Pengganti Solar Yang Terbuat Dari Ekstraksi Minyak Jarak

Pagar, Trubus Agrisarana, Surabaya.

Takahashi, Y., Sakurai,H., Inui,E., Namai,S., Sato,T., 2011. Radiocarbon Measurement Of Biodiesel Fuel Using The

Liquid Scintillation Counter Quantulus. In: Cassette, P.(Ed.), LSC 2010, Advances in Liquid Scintillation

Spectrometry. Radiocarbon, Tuscon, pp.41–46.

Tjahaja, P.I., dan Mutiah, 2000, Metode Pencacahan Sintilasi Cair: Salah Satu Alternatif untuk Pengukuran α dan β

Total dalam Sampel Lingkungan, Jurnal Sains dan Tekhnologi Nuklir Indonesia, 1 (1), 31-46.

Varlam, C, Stefanescu, I., Varlam, M., Popescu, I., Faurescu, I., 2007, Applying the Direct Absorption Method And

LSC For 14C Concentration Measurement In Aqueous Samples, Radiocarbon, 49(2), 281-289

Wirawan, S.S., dan A.H. Tambunan, 2006, The Current Status and Prospects of Biodiesel Development in Indonesia : A

Review, Prosiding of Third Asia Biomass Workshop, 16 November 2006. Tsukuba. Japan. 1-15.

Yuliati, H., Akhadi, M., 2005, For Cosmogenic Radionuclide Dating, Center for Biomedical Radiation and Nuclear

Safety. Radiation Center. Batam.

Yunoki, S., Saito, M., 2009. A Simple Method To Determine Bioethanol Contentin Gasoline Using Two-Step

Extraction And Liquid Scintillation Counting. Bioresour. Technol. 100: 6125–6129.


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